t-BuOOHとCe(4+)の反応
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t-BuOOHとCe(4+)の反応
Clareらは，Ce(IV)とt-BuOOHの二次反応速度定数kは,0.4M硫酸中です，1.3×10^(+4) [/M/s]であったと述べている1)．
(1) EPR detection of the unstable tert-butylperoxyl radical adduct of the spin trap 5,5-dimethyl-1-pyrroline N-oxide: a combined spin-trapping and continuous-flow investigation
Clare M. Jones and Mark J. Burkitt , j. chem. soc., perkin trans. 2,12,2044(2002).
Clare M. Jones and Mark J. Burkitt , j. chem. soc., perkin trans. 2,12,2044(2002).
この反応の更新